Revisiting observability in polydisperse systems: “real” polydispersity

2011/07/17 // 1 Comment

edited on 2011-07-20 14:51 to add equation defining observability Of course I could not leave you hanging after the last post with that question “does the observability still scale with the radius squared for samples with more than two particles?”. Short answer: yes. Long answer: mostly, with some interesting lessons w.r.t. q-angles and limitations. Click “more” to read on…


Observability in polydisperse systems. What is all the accuracy for?

2011/06/30 // 0 Comments

Abstract of this post: In this post, I will show that for a spherical two-particle system, the observability of the smaller particle scales with the inverse squared radius, quite different from the scattering power, which scales with the radius to the sixth power (volume squared). This means that scattering data with 1% error can be used to distinguish at most particles 1/20th the size of the largest particle present, and data with 0.1% error can be used to observe single particles at most 1/50th of the size of the largest particle. Beyond this, only proportional numbers of smaller particles can be observed. Additionally the point of maximum observability is determined to be at q*Rg~2.6 for numeric examples, and q*Rg~2.45 for an algebraic approximation.